A solution which is${10^{ - 3}}\;{\rm{M }}\;{\rm{each}}\;{\rm{ in }}\;{\rm{M}}{{\rm{n}}^{2 + }},\,{\rm{F}}{{\rm{e}}^{2 + }}\;,{\rm{Z}}{{\rm{n}}^{2 + }}\;{\rm{and }}\;{\rm{H}}{{\rm{g}}^{2 + }}$ is treated with ${10^{ - 16\;}}M$ sulphide ion. If ${K_{{\rm{sp}}}}\;{\rm{of}}\;{\rm{ MnS}},\;{\rm{FeS}},\;{\rm{ZnS }}\;{\rm{and}}\;{\rm{ HgS}}\,{\rm{ are}}\;{10^{ - 15}},$ ${10^{ - 23}},\;{10^{ - 20}}\;{\rm{and}}\;{10^{ - 54}}$ respectively, which one will precipitate first?